Abstract/Details

Synthesis and characterization of novel carbosilane dendrimers as supports


2004 2004

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Abstract (summary)

Cyclic siloxane and polyhedral oligomeric silsesquioxane cages were used as core elements in the synthesis of vicinal amino alcohol capped dendrimers. Through divergent, repetitive hydrosilation/vinylation, dendrimers with varying degrees of branching were produced. Vinyl termini were subjected to hydrosilation, and subsequent hydrogenation to yield silyl hydride termini, which were then reacted with vinylbenzylchloride via hydrosilation to give dendrimers with benzyl chloride linkers. In separate studies, R-4-hydroxyphenylglycine was reduced to its corresponding amino alcohol, and methods for side chain attachment were considered.

Indexing (details)


Subject
Organic chemistry
Classification
0490: Organic chemistry
Identifier / keyword
Pure sciences
Title
Synthesis and characterization of novel carbosilane dendrimers as supports
Author
De Selm, Luke C
Pages
99 p.
Number of pages
99
Publication year
2004
Degree date
2004
School code
6080
Source
MAI 43/04, p. 1273, Aug 2005
Place of publication
Ann Arbor
Country of publication
United States
ISBN
9780496914234, 0496914235
Advisor
Buonara, Paul T
University/institution
California State University, Long Beach
University location
United States -- California
Degree
M.S.
Source type
Dissertations & Theses
Language
English
Document type
Dissertation/Thesis
Dissertation/thesis number
1424798
ProQuest document ID
305036724
Copyright
Copyright UMI - Dissertations Publishing 2004
Document URL
http://search.proquest.com/docview/305036724
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