Abstract/Details

Advanced approaches for modeling trace metal sorption in aqueous systems


2003 2003

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Abstract (summary)

An extensive collection of new macroscopic and spectroscopic data was used to assess the ability of the modified triple-layer model (TLM) to predict single-solute lead (Pb) and zinc (Zn) sorption onto 2-line ferrihydrite over a wide range of conditions in both single- and multi-equilibrium-stage systems. Regression of constant-pH isotherm data, together with potentiometric titration and pH edge data, was found to be a much more rigorous test of a surface complexation model than fitting pH edge data alone. When combined with spectroscopic data, the choices of feasible surface species/site types were limited to a few. Excellent fits of the Pb sorption data were obtained with a two-species, one-site model using the species pairs (≡FeO)2Pb/≡FeOHPb 2+ and (≡FeO)2Pb/≡FeOPb+-NO 3. For Zn, a one-species, one-Zn-sorption-site model using the bidentate complex, (≡FeO)2Zn, provided excellent fits of the data. Surprisingly, best-fit equilibrium “constants” for the Pb and Zn surface complexes and, for Zn, the density of Zn sorption sites had to be varied with pH to fit the data. A surface activity coefficient term was also required for both metals to reduce the ionic-strength dependence of sorption.

Experimental data and modeling results showed that a multistage sorption system can significantly reduce Pb and Zn effluent concentrations for the same total amount of sorbent or, alternatively, dramatically lower sorbent consumption for the same effluent concentration. Model predictions were made using the modified TLM integrated into a steady-state, multistage, equilibrium adsorber model within the OLI Software (OLI Systems, Inc., Morris Plains, NJ). Engineering screening evaluations showed that a 2- to 3-stage sorption process can provide significant economic savings when compared to a 1-stage process operating with the same target effluent metal concentration. Additional equilibrium stages beyond 2 or 3 provide diminishing economic returns.

Finally, using a novel uncertainty analysis module within the OLI Software, error propagation through the modified TLM was studied for both metals using isotherm, pH edge, and multistage treatment data. When coupled with the nonlinear equation solver's gain matrix, the linearized local extrapolation and error propagation models in the OLI code provided a satisfactory alternative to a more rigorous, time-consuming Monte Carlo simulation.

Indexing (details)


Subject
Soil sciences;
Environmental science;
Geochemistry
Classification
0481: Soil sciences
0768: Environmental science
0996: Geochemistry
Identifier / keyword
Health and environmental sciences, Earth sciences, Biological sciences, Aqueous systems, Ferrihydrite, Metal sorption, Remediation, Trace metal sorption
Title
Advanced approaches for modeling trace metal sorption in aqueous systems
Author
Dyer, James Arthur
Number of pages
371
Publication year
2003
Degree date
2003
School code
0060
Source
DAI-B 64/01, Dissertation Abstracts International
Place of publication
Ann Arbor
Country of publication
United States
ISBN
0493984585, 9780493984582
Advisor
Sparks, Donald L.
University/institution
University of Delaware
University location
United States -- Delaware
Degree
Ph.D.
Source type
Dissertations & Theses
Language
English
Document type
Dissertation/Thesis
Dissertation/thesis number
3077875
ProQuest document ID
305345983
Copyright
Database copyright ProQuest LLC; ProQuest does not claim copyright in the individual underlying works.
Document URL
http://search.proquest.com/docview/305345983
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