Mechanisms of phosphoryl transfer. Kinetics and thermodynamics of phosphoryl transfer with nitrogen and oxygen bases: The metaphosphate question; the nature of the transition state; the effects on reactivity of electrostatic repulsion, steric factors and hydrogen bonding; the high reactivity of alpha-effect nucleophiles and fluoride ion; and metal ion catalysis, inhibition, and effects on transition state structure
Herschlag, Daniel.
Brandeis University ProQuest Dissertations Publishing, 1989. 8910665.